Section 1: Product Identification SAFETY DATA SHEET (SDS) RESIDUAL SPRAY
Manufactured For disribution by:
Winner Industrial supply, Inc.
154-a west Foothill Blvd
Upland .Ca. 91786
This Material Safety Data Sheet contains environmental, health and toxicology information for your employees. Please make sure this information is given to them. It also contains information to help you meet community Right To Know emergency response reporting requirements under SARA TITLE III and many other laws. If you resell this product, this SDS must be given to the buyer or the information incorporated in your SDS. Product identifier Product Name: RESIDUAL SPRAY EPA Registration Number: 84396-12 Other means of identification Part Code: 27050 Recommended use of the chemical and restrictions on use: Recommended Use: A residual insecticide for crawling insects.
Details of the supplier of the safety data sheet Manufacturer Address: Sungro Products, LLC. 810 E. 18th St. Los Angeles, CA 90021
FAX #: (213)747-0942 Telephone Number: (800)463-9179(800)463-9179 FREE, or (213) 747-4125(213) 747-4125 e-Mail Address: email@example.com Emergency telephone numbers: 24 Hour TRANSPORTATION Emergency: INFOTRAC®: (800) 535-5053(800) 535-5053 FREE – Contract #78479 International: (352) 323-3500(352) 323-3500 24 Hour MEDICAL Emergency: Safety Call®: (888) 740-8712(888) 740-8712 FREE, or (952) 852-9509(952) 852-9509
Comments: SUNGRO PRODUCTS
Hours of operation are 7:30 am to 4:00 pm PCT.
For MEDICAL EMERGENCIES or PESTICIDE INCIDENTS,
call 24 hours a day to (888) 740-8712(888) 740-8712 FREE, or (952) 852-9509(952) 852-9509.
Section 2: Hazard(s) Identification Classification OSHA
Regulatory Status: This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Eye irritation Category 2A Skin irritation Category 2 Aspiration hazard Category 1 Specific target organ toxicity – single exposure a Category 3A (central nervous system) Flammable liquids Category 4 Page 2 of 8 GHS Label elements Emergency Overview DANGER Hazard statements
• H315 – Causes skin irritation
• H304 – May be fatal if swallowed and enters airways
• H402 – Harmful to aquatic life, birds and other wildlife.
• H227 – Combustible liquid
• H336- May cause drowsiness or dizziness.
Appearance: Colorless to light Yellow Physical state: Liquid Odor: Solvent Precautionary Statements – Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces. – No smoking P261 Avoid breathing fume, mist, vapor, or spray. P264 Wash skin thoroughly after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements – Response: P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician P302 +352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 + P312: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell.
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P331 Do NOT induce vomiting P370 + P378 In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements – Storage: P405 Store locked up P403 + P235 Store in a well-ventilated place. Keep cool Precautionary Statements – Disposal: P501 Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC): Not applicable.
3.COMPOSITION/ INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% 2-Isopropoxyphenyl ( propoxur) ((methylcarbamate 114-26-1 1 2-butoxy ethanol 111-76-2 5-20 Petroleum distillates, hydrotreated light 64742-47-8 80-95 *The exact percentage (concentration) of composition has been withheld as a trade secret. Comments: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications.
4. FIRST AID MEASURES Aspiration pneumonia hazard:
• May be fatal if swallowed and enters airways.
Description of first aid measures: Ingestion: If swallowed, IMMEDIATELY call a poison control center or doctor for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or a doctor. Never give anything by mouth to an unconscious person. Page 3 of 8 Eye contact: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice.
Skin Contact: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice.
Inhalation: Remove affected person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Self-protection of the First Responder: Use personal protective equipment as required.
Note to physicians: Containspetroleumdistillates-vomitingmaycauseaspirationpneumonia.
Symptoms of Poisoning: A sense of “tightness” in chest. Sweating. Contracted pupils. Stomach pains. Vomiting and diarrhea. Antidote: Administer atropine sulfate in therapeutic doses. Repeat as necessary to point of tolerance. Compound inhibits cholinesterase resulting in stimulation of the central nervous system. The parasympathetic nervous system and the somatic motor nerves. Do not give morphine. Watch for pulmonary edema which may develop in serious cases of poisoning even after 12 hours. At first sign of pulmonary edema the patient should be placed in an oxygen tent and treated symptomatically.
5. FIRE-FIGHTING MEASURES Suitable extinguishing media: Carbon dioxide (CO2). Unsuitable extinguishing media: High volume water jet. Hazardous combustion products: Carbon monoxide. Carbon dioxide (CO2). Propoxur may generate isocyanates upon decomposition. Specific hazards arising from the chemical: Do not allow run-off from fire fighting to enter drains or water courses. Keep product and empty container away from heat and sources of ignition.
Risk of ignition. Protective equipment and precautions for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
NFPA Flammable and Combustible Liquids Classification: Combustible Liquid Class IIIA NFPA Health hazards 2 Flammability 2 Instability 0 Physical /Chemical Properties – HMIS Health hazards 2 Flammability 2 Physical hazards 0 Personal protection X 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions: Use personal protective equipment as required. Remove all sources of ignition. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Pay attention to flashback. Take precautionary measures against static discharges.
Page 4 of 8 Environmental precautions: Prevent entry into waterways, sewers, basements or confined areas. Do not flush into surface water or sanitary sewer system. Prevent further leakage or spillage if safe to do so. Prevent product from entering drains.
See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment: Prevent further leakage or spillage if safe to do so. Methods for cleaning up: Cover liquid spill with sand, earth or other non-combustible absorbent material. Pick up and transfer to properly labeled containers. Soak up with inert absorbent material. Dam up. Take precautionary measures against static discharges.
7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling: Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Wash contaminated clothing before reuse. Do not breathe dust/fume/gas/mist/vapors/spray. Do not eat, drink or smoke when using this product. Use with local exhaust ventilation. All equipment used when handling the product must be grounded. Keep away from heat/sparks/open flames/hot surfaces. – No smoking. Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapors).
For more information, see product label. Applicators and handlers must wear long sleeved shirt, long pants, shoes and socks and chemical resistant gloves. Conditions for safe storage, including any incompatibilities Storage Conditions: Keep container tightly closed in a dry and well-ventilated place. Keep out of the reach of children. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Keep containers tightly closed in a cool, well-ventilated place. Keep away from heat. Keep in properly labeled containers. For more information, see product label. Periodically inspect stored material.
8. EXPOSURE CONTROLS/ PERSONAL PROTECTION
Control parameters Exposure Guidelines: This product, as supplied, does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Appropriate engineering controls
Engineering Controls: Safety showers Eyewash stations Ventilation systems Chemical Name ACGIH TLV OSHA Z-1 NIOSH REL Supplier OEL Propoxur 114-26-1 TWA: 0.5 mg/m3 TWA: 0.5 mg/m3 – – 2-butoxy ethanol TWA: 20 ppm TWA: 240 mg/m3 50 ppm TWA: 5 ppm 24 mg/m3 Petroleum distillates, hydrotreated light 64742-47-8 TWA: 200 mg/m3 (aas total hydrocarbon vapor)
TWA: 500 ppm 2000 mg/m3 – TWA: 100 ppm
TWA: 525 mg/m3 Page 5 of 8 Individual protection measures, such as personal protective equipment Eye/face protection: Tight sealing safety goggles or full face shield.
Skin and body protection: Wear chemical resistant gloves and protective clothing.
Respiratory protection: If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved pesticide respirator should be worn.
General Hygiene Considerations: When using do not eat, drink or smoke. Regular cleaning of equipment, work area and clothing is recommended. Wash any contaminated clothing separately from non contaminated clothes.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties: Physical state: Liquid Appearance: Clear to light yellow Odor: Solvent Odor threshold: No information available Color (Gardner Scale): No information available
Property: Values: Comment: • Method pH: No information available Not applicable; immiscible in water. Melting point / freezing point: No information available Boiling point / boiling range: 330°F – 500°F Flash point: 166.0 °F Tag Closed Cup Flame Extension Test: No information available Evaporation rate: <0.1 Flammability (solid, gas): No information available Upper flammability limit (UEL): No information available Lower flammability limit (LEL): No information available Vapor pressure: No information available Vapor density: Heavier than air.
Partition coefficient; n-Octanol/ No information available Water: Autoignition temperature: No information available
Decomposition temperature: No information available
Kinematic viscosity: No information available Dynamic viscosity: No information available Refractive Index: No information available Specific gravity: 0.84 g/cm3 @ 20 °C Density: 7.0 lbs/gal Miscibility/ Solubility: Water: Immiscible Alcohol: Miscible Petroleum distillates: Miscible Aromatic solvents: Miscible
10. STABILITY AND REACTIVITY Reactivity: No data available Chemical stability: Stable under recommended storage conditions. Possibility of Hazardous Reactions: Vapors may form explosive mixture with air. Hazardous polymerization: Hazardous polymerization does not occur. Page 6 of 8 Conditions to avoid: Heat, flames and sparks. Incompatible materials: Strong oxidizing agents; alkaline materials. Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide (CO2), methyl isocyanate.
11. TOXICOLOGICALINFORMATION Acute Toxicity Components: 111-76-2: 64742-47-8: 114-26-1 (99.6% technical): Acute oral toxicity LD50 (rat): >500 mg/kg; LD50 (rat): >5000 mg/kg; LD50 (rat/male): >69 mg/kg; rat/female: 47mg/kg Acute inhalation toxicity LC50 (rat); 4500 ppm- 4h No data available LC50 (rat);0.654 mg/L (dust) Acute dermal toxicity LD50 (rabbit, male and female): LD50 (rabbit, male and female): LD50 (rat): >5000 mg/kg >1100 mg/kg >2,000 mg/kg Skin corrosion/irritation: Irritating to skin May cause irritation in susceptible persons Non irritating Serious eye damage/ Irritating to eyes Severe eye irritation. Minimal irritation Irritation Respiratory or skin Buehler test, guinea pig, did not Buehler test, guinea pig, did not Not a dermal sensitizer Sensitization cause sensitization on lab animals cause sensitization on lab animals Germ cell mutagenicity Not classified Not classified Not a mutagen Carcinogenicity Not classified Not classified ACGIH: Group A3 Reproductive toxicity Not classified Not classified No information available STOT single exposure Not data available Not data available No information available STOT repeated exposure Not data available Not data available No information available Aspiration toxicity Not data available May be fatal if swallowed No information available and enters airways
12. ECOLOGICALINFORMATION Ecotoxicity: Components: 111-76-2: 64742-47-8: 114-26-1 (99.6% technical): Toxicity to fish: LC50(rainbow trout):1474 mg/L LC50(rainbow trout): 25 mg/L LC50(rainbow trout): 3.7ppm Toxicity to aquatic Invertebrates: EC50(water flea): 1800 mg/L EC50(water flea): 1.4 mg/L EC50(water flea): 0.15 mg/L Toxicity to algae: EC50(green algae): 911 mg/L EC50(green algae): 1-3 mg/L No information available Persistence and Degradability: Readily biodegradeable Readily biodegradeable Biodegradeable Bioaccumulation: log Pow: 0.83 log Pow: 3.3 – may accumulate No affinity to accumulate Mobility in soil: No data available Adsorbs on soil Mobile Environmental hazards (EPA): This product is toxic to wildlife and aquatic invertebrates. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA.
13. DISPOSALCONSIDERATIONS Waste treatment methods Disposal of wastes: Disposal should be in accordance with applicable regional, national and local laws and regulations. For more information, see product label. Contaminated packaging: For more information, see product label.
14. TRANSPORTINFORMATION DOT (Department of Transportation) Page 7 of 8 Proper Shipping Name: Insecticides, Insect or Animal Repellent, Liquid Hazard Class: Non-Hazardous B/L Freight Classification: NMFC item 102120; LTL class 60 Other Shipping Information: This material is not regulated as a hazardous material by the DOT in available quantities. RQ (propoxur) 100 lbs. – No unit sizes contain this amount. Air (IATA/ ICAO) Proper Shipping Name: Insecticides, Insect or Animal Repellent, Liquid Hazard Class: Non-Hazardous Vessel (IMO/ IMDG) Proper Shipping Name: Insecticides, Insect or Animal Repellent, Liquid Hazard Class: Non-Hazardous
15. REGULATORYINFORMATION US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 – Threshold Values % 2-butoxy ethanol CAS#111-76-2 14.0-15.0 Propoxur CAS# 114-26-1 1.0 SARA 311/312 Hazard Categories Acute health hazard Fire hazard CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material Chemical Name HazardousSubstances RQs RCRA waste No.
Propoxur 114-26-1 RQ 100 lb (45.4 kg) U411 US State Regulations: California Proposition 65: This product contains, Propoxur – CAS # 114-26-1, which is listed by the state to cause cancer, birth defects and other reproductive harm under the statute.
Page 8 of 8 U.S. EPA Label Information: EPA
Registration Number: 84396-12
Difference between SDS and EPA (FIFRA) Pesticide label: This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law.
These requirements differ from the classification criteria and hazard information required for Safety Data Sheets (SDS), and for workplace labels of non-pesticide chemicals.
The pesticide label also includes other important information, including directions for use. The hazard information required on the pesticide label is reproduced below: Signal word: CAUTION PrecautionaryStatements:
• Harmful if swallowed.
• Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals.
International: No information available
16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION.
Issue Date: 13-Apr-2015
Revision Date: 13-Apr-2015
Revision Note: New SDS. GHS – Classification. SDS Prepared By: Regulatory Department. Disclaimer: The data contained herein are based on information currently available to Sungro Products, LLC and,to the best of our knowledge, are accurate and based on sound expert opinion. Our statements herein, however, are not to be taken as a warranty or representation for which Sungro Products, LLC assumes legal responsibility. End of Safety Data Sheet.
1264 South Waterman
San Bernardino, CA 92408